dc.contributor.authorCheng, Jiajia
dc.contributor.authorHuang, Zhijian
dc.contributor.authorChi, Robin Yonggui
dc.date.accessioned2014-05-26T01:29:53Z
dc.date.available2014-05-26T01:29:53Z
dc.date.copyright2013en_US
dc.date.issued2013
dc.identifier.citationCheng, J., Huang, Z., & Chi, Y. R. (2013). NHC Organocatalytic Formal LUMO Activation of ,β-Unsaturated Esters for Reaction with Enamides. Angewandte Chemie International Edition, 52(33), 8592–8596.en_US
dc.identifier.issn1433-7851en_US
dc.identifier.urihttp://hdl.handle.net/10220/19438
dc.description.abstractAn effective wake-up call: Stable ,β-unsaturated esters were activated by the addition of a chiral N-heterocyclic carbene (NHC) organocatalyst, and the resulting reactive Michael acceptor intermediates reacted with enamide nucleophiles to furnish optically pure products (see scheme; Ts=p-toluenesulfonyl). These products can be converted readily into bioactive δ-lactams, piperidines, and their derivatives.en_US
dc.language.isoenen_US
dc.relation.ispartofseriesAngewandte chemie international editionen_US
dc.rights© 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en_US
dc.subjectDRNTU::Science::Chemistry
dc.titleNHC organocatalytic formal LUMO activation of α,β-unsaturated esters for reaction with enamidesen_US
dc.typeJournal Article
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doihttp://dx.doi.org/10.1002/anie.201303247
dc.identifier.rims173635


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