dc.contributor.authorTeo, Yew Chin
dc.contributor.authorPan, Yuanhang
dc.contributor.authorTan, Choon Hong
dc.date.accessioned2014-06-16T03:57:07Z
dc.date.available2014-06-16T03:57:07Z
dc.date.copyright2013en_US
dc.date.issued2013
dc.identifier.citationTeo, Y. C., Pan, Y., & Tan, C. H. (2013). Organic Dye-Photocatalyzed Acylnitroso Ene Reaction. ChemCatChem, 5(1), 235-240.en_US
dc.identifier.issn1867-3880en_US
dc.identifier.urihttp://hdl.handle.net/10220/19790
dc.description.abstractRose bengal, an inexpensive and readily available organic dye, is demonstrated to be a photoredox catalyst for the formation of transient acylnitroso intermediates under visible light irradiation. This method is operationally simple and uses air as the terminal oxidant. Reactions of acylnitroso with a range of functionalized alkenes give intermolecular acylnitroso ene products in moderate to good yields. This is an environmentally friendly allylic amination methodology that avoids the use of metal catalysts and stoichiometric amount of oxidants. A plausible reaction mechanism is proposed on the basis of singlet oxygen and fluorescence quenching studies.en_US
dc.language.isoenen_US
dc.relation.ispartofseriesChemcatchemen_US
dc.rights© 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en_US
dc.subjectDRNTU::Science::Chemistry::Organic chemistry
dc.titleOrganic dye-photocatalyzed acylnitroso ene reactionen_US
dc.typeJournal Article
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doihttp://dx.doi.org/10.1002/cctc.201200435


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