dc.contributor.authorAravindan, Vanchiappan
dc.contributor.authorSundaramurthy, Jayaraman
dc.contributor.authorJain, Akshay
dc.contributor.authorKumar, Palaniswamy Suresh
dc.contributor.authorLing, Wong Chui
dc.contributor.authorRamakrishna, Seeram
dc.contributor.authorSrinivasan, Madapusi P.
dc.contributor.authorMadhavi, Srinivasan
dc.date.accessioned2014-09-10T06:58:37Z
dc.date.available2014-09-10T06:58:37Z
dc.date.copyright2014en_US
dc.date.issued2014
dc.identifier.citationAravindan, V., Sundaramurthy, J., Jain, A., Kumar, P. S., Ling, W. C., Ramakrishna, S., et al. (2014). Unveiling TiNb2O7 as an Insertion Anode for Lithium Ion Capacitors with High Energy and Power Density. ChemSusChem, 7(7), 1858-1863.en_US
dc.identifier.issn1864-5631en_US
dc.identifier.urihttp://hdl.handle.net/10220/20491
dc.description.abstractThis is the first report of the utilization of TiNb2O7 as an insertion-type anode in a lithium-ion hybrid electrochemical capacitor (Li-HEC) along with an activated carbon (AC) counter electrode derived from a coconut shell. A simple and scalable electrospinning technique is adopted to prepare one-dimensional TiNb2O7 nanofibers that can be characterized by XRD with Rietveld refinement, SEM, and TEM. The lithium insertion properties of such electrospun TiNb2O7 are evaluated in the half-cell configuration (Li/TiNb2O7) and it is found that the reversible intercalation of lithium (≈3.45 mol) is feasible with good capacity retention characteristics. The Li-HEC is constructed with an optimized mass loading based on the electrochemical performance of both the TiNb2O7 anode and AC counter electrode in nonaqueous media. The Li-HEC delivers very high energy and power densities of approximately 43 Wh kg−1 and 3 kW kg−1, respectively. Furthermore, the AC/TiNb2O7 Li-HEC delivers a good cyclability of 3000 cycles with about 84 % of the initial value.en_US
dc.language.isoenen_US
dc.relation.ispartofseriesChemSusChemen_US
dc.rights© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en_US
dc.subjectDRNTU::Engineering::Materials::Metallic materials
dc.titleUnveiling TiNb2O7 as an insertion anode for lithium ion capacitors with high energy and power densityen_US
dc.typeJournal Article
dc.contributor.researchEnergy Research Institute @NTUen_US
dc.contributor.schoolSchool of Materials Science and Engineeringen_US
dc.identifier.doihttp://dx.doi.org/10.1002/cssc.201400157


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