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|Title:||Isolation of a bis(oxazol-2-ylidene)-phenylborylene adduct and its reactivity as a boron-centered nucleophile||Authors:||Vidović, Dragoslav
Kong, Ling Bing
|Keywords:||DRNTU::Science::Chemistry||Issue Date:||2014||Source:||Kong, L., Li, Y., Ganguly, R., Vidovic, D., & Kinjo, R. (2014). Isolation of a Bis(oxazol-2-ylidene)-Phenylborylene Adduct and its Reactivity as a Boron-Centered Nucleophile. Angewandte Chemie International Edition, 53(35), 9280-9283.||Series/Report no.:||Angewandte Chemie international edition||Abstract:||An isolable phenylborylene species supported by two oxazol-2-ylidene ligands was synthesized and structurally characterized. Computational studies revealed the presence of lone-pair electrons on the boron atom in this molecule; therefore, there are eight electrons around the three-coordinate boron center. The nucleophilic property was confirmed by the reactions with trifluoromethanesulfonic acid and [(thf)Cr(CO)5], which gave the corresponding conjugate acid and a chromium–borylene complex, respectively.||URI:||https://hdl.handle.net/10356/105355
|ISSN:||1433-7851||DOI:||10.1002/anie.201405201||Rights:||© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.||Fulltext Permission:||none||Fulltext Availability:||No Fulltext|
|Appears in Collections:||SPMS Journal Articles|
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