Dihaloborenium cations stabilized by a four-membered N-heterocyclic carbene : electron deficiency compensation by asymmetric structural changes
Tay, Madelyn Qin Yi
Date of Issue2014
School of Physical and Mathematical Sciences
The synthesis, characterization and X-ray analysis of dichloro- and dibromo-borenium cations stabilized by a 4-membered carbene are reported. The ligand's structural changes, atypical for similar systems, were caused by coordination to electron deficient fragments and its CN2P ring strain.
DRNTU::Science::Chemistry::Organic chemistry::Organic analysis
© 2014 Royal Society of Chemistry. This is the author created version of a work that has been peer reviewed and accepted for publication by Dalton Transactions, Royal Society of Chemistry. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1039/C4DT01210K].