dc.contributor.authorTeo, Wei Zhe
dc.contributor.authorPumera, Martin
dc.date.accessioned2014-09-15T02:49:49Z
dc.date.available2014-09-15T02:49:49Z
dc.date.copyright2014en_US
dc.date.issued2014
dc.identifier.citationTeo, W. Z., & Pumera, M. (2014). Direct voltammetric determination of redox-active iron in carbon nanotubes. ChemPhysChem, 15(17), 3819-3823.en_US
dc.identifier.issn1439-4235en_US
dc.identifier.urihttp://hdl.handle.net/10220/20682
dc.description.abstractWith the advances in nanotechnology over the past decade, consumer products are increasingly being incorporated with carbon nanotubes (CNTs). As the harmful effects of CNTs are suggested to be primarily due to the bioavailable amounts of metallic impurities, it is vital to detect and quantify these species using sensitive and facile methods. Therefore, in this study, we investigated the possibility of quantifying the amount of redox-available iron-containing impurities in CNTs with voltammetric techniques such as cyclic voltammetry. We examined the electrochemistry of Fe3O4 nanoparticles in phosphate buffer solution and discovered that its electrochemical behavior could be affected by pH of the electrolyte. By utilizing the unique redox reaction between the iron and phosphate species, the redox available iron content in CNTs was determined successfully using voltammetry.en_US
dc.language.isoenen_US
dc.relation.ispartofseriesChemPhysChemen_US
dc.rights© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheimen_US
dc.subjectDRNTU::Science::Chemistry::Physical chemistry
dc.titleDirect voltammetric determination of redox-active iron in carbon nanotubesen_US
dc.typeJournal Article
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doihttp://dx.doi.org/10.1002/cphc.201402384


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