Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/101497
Title: Coordination polymers from 1-D to 3-D assembled from disulfonate ligands : structures and luminescent properties
Authors: Zhang, Xiao-Wei
Huang, Wei-Yan
Xiong, Yan-Ju
Huang, Pei-Ling
Wang, Ning
Ye, Xiao-Ping
Huang, Qiu-Hong
Yue, Shan-Tang
Keywords: DRNTU::Engineering::Materials::Organic/Polymer electronics
Issue Date: 2014
Source: Ye, X.-P., Xiong, Y.-J., Huang, P.-L., Wang, N., Zhang, X.-W., Huang, W.-Y., et al. (2014). Coordination polymers from 1-D to 3-D assembled from disulfonate ligands : structures and luminescent properties. Inorganic chemistry communications, 48, 120-126.
Series/Report no.: Inorganic chemistry communications
Abstract: Four rare earth organodisulfonate coordination polymers, {[Tb2(phen)4(nds)3(H2O)2]·4H2O}n (1), {[Ln(phen)(nds)(OH)]}n[Ln = Sm (2), Nd (3)], {[Tb(phen)2(nds)0.5(OH)·H2O]·(nds)0.5}n (4), were synthesized under the solvothermal conditions by using ligands 2,6-naphthalenedisulfonate (L = nds) and 1,10-phenanthroline (L′ = phen). Single-crystal X-ray diffraction reveals that compounds 1 and 4 exhibit different 1-D and 2-D crystal structures just owing to the single difference of stoichiometric ratio of the reactants in the synthesis process. Compounds 2 and 3 show 3-D structures with similar Ln coordination mode. Besides, the photoluminescent property in solid state of 1 was investigated in detail.
URI: https://hdl.handle.net/10356/101497
http://hdl.handle.net/10220/24187
ISSN: 1387-7003
DOI: http://dx.doi.org/10.1016/j.inoche.2014.08.026
Rights: © 2014 Elsevier B.V.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:MSE Journal Articles

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