dc.contributor.authorTan, Boon-Hong
dc.contributor.authorYoshikai, Naohiko
dc.date.accessioned2014-12-09T02:41:29Z
dc.date.available2014-12-09T02:41:29Z
dc.date.copyright2014en_US
dc.date.issued2014
dc.identifier.citationTan, B.-H., & Yoshikai, N. (2014). Cobalt-catalyzed addition of arylzinc reagents to norbornene derivatives through 1,4-cobalt mgration. Organic letters, 16(12), 3392-3395.en_US
dc.identifier.urihttp://hdl.handle.net/10220/24361
dc.description.abstractA cobalt–diphosphine catalyst promotes the addition of an arylzinc reagent to a norbornene derivative to afford o-(2-exo-norbornyl)arylzinc species. This “migratory arylzincation” reaction is considered to involve insertion of norbornene into an arylcobalt species, alkyl-to-aryl 1,4-cobalt migration, and transmetalation between the resulting o-(2-exo-norbornyl)arylcobalt species and the arylzinc reagent. The o-(2-exo-norbornyl)arylzinc species can be intercepted by common organic electrophiles under copper or palladium catalysis.en_US
dc.description.sponsorshipNRF (Natl Research Foundation, S’pore)en_US
dc.format.extent6 p.en_US
dc.language.isoenen_US
dc.relation.ispartofseriesOrganic lettersen_US
dc.rights© 2014 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Organic Letters, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [Article DOI: http://dx.doi.org/10.1021/ol501449j].en_US
dc.subjectDRNTU::Science::Chemistry
dc.titleCobalt-catalyzed addition of arylzinc reagents to norbornene derivatives through 1,4-cobalt mgrationen_US
dc.typeJournal Article
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doihttp://dx.doi.org/10.1021/ol501449j
dc.description.versionAccepted versionen_US


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