dc.contributor.authorTeo, Jing Wei
dc.contributor.authorSridevi, Venugopal Shanmugham
dc.contributor.authorLeong, Weng Kee
dc.identifier.citationTeo, J. W., Sridevi, V. S., & Leong, W. K. (2014). N-metallacycles from [Cp*MX2]2 and alkynylpyridines : synthesis, reaction pathway, and romaticity. Organometallics, 33(5), 1174-1180.en_US
dc.description.abstractThe reaction of [Cp*MX2]2 (M = Rh or Ir, X = Cl, Br, or I) with alkynylpyridines afforded halogen-substituted N-metallacyclic complexes. The reaction pathway has been examined through deuterium labeling and other experiments and computational studies and is proposed to proceed via halide dissociation followed by attack at the alkyne. These N-metallacycles exhibit aromaticity and undergo Sonogashira coupling reactions.en_US
dc.description.sponsorshipMOE (Min. of Education, S’pore)en_US
dc.format.extent12 p.en_US
dc.rights© 2014 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Organometallics, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [Article DOI: http://dx.doi.org/10.1021/om401154c].en_US
dc.subjectDRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
dc.titleN-metallacycles from [Cp*MX2]2 and alkynylpyridines : synthesis, reaction pathway, and romaticityen_US
dc.typeJournal Article
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.description.versionAccepted versionen_US

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