dc.contributor.authorXiao, Peng
dc.contributor.authorSk, Mahasin Alam
dc.contributor.authorThia, Larissa
dc.contributor.authorGe, Xiaoming
dc.contributor.authorLim, Rern Jern
dc.contributor.authorWang, Jing-Yuan
dc.contributor.authorLim, Kok Hwa
dc.contributor.authorWang, Xin
dc.date.accessioned2014-12-11T02:03:30Z
dc.date.available2014-12-11T02:03:30Z
dc.date.copyright2014en_US
dc.date.issued2014
dc.identifier.citationXiao, P., Sk, M. A., Thia, L., Ge, X., Lim, R. J., Wang, J.-Y., et al. (2014). Molybdenum phosphide as an efficient electrocatalyst for the hydrogen evolution reaction. Energy & environmental science, 7(8), 2624-2629.en_US
dc.identifier.urihttp://hdl.handle.net/10220/24428
dc.description.abstractElectrochemical production of hydrogen from water has been directed to the search for non-noble metal based and earth-abundant catalysts. In this work, we propose a novel cost-effective catalyst, molybdenum phosphide that exhibits high activity towards the hydrogen evolution reaction (HER) in both acid and alkaline media even in bulk form. Comparative analysis of Mo, Mo3P and MoP as catalysts for HER clearly indicates that phosphorization can potentially modify the properties of the metal and different degrees of phosphorization lead to distinct activities and stabilities. Theoretical calculations by density functional theory also show that a simple phosphorization of molybdenum to form MoP introduces a good ‘H delivery’ system which attains nearly zero binding to H at a certain H coverage. With the combination of experimental results and theoretical calculations, this work has enlightened a new way of exploring cost-effective catalysts for HER.en_US
dc.format.extent6 p.en_US
dc.language.isoenen_US
dc.relation.ispartofseriesEnergy & environmental scienceen_US
dc.rightsThis article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.en_US
dc.subjectDRNTU::Science::Chemistry::Physical chemistry::Catalysis
dc.titleMolybdenum phosphide as an efficient electrocatalyst for the hydrogen evolution reactionen_US
dc.typeJournal Article
dc.contributor.researchResidues and Resource Reclamation Centreen_US
dc.contributor.schoolSchool of Chemical and Biomedical Engineeringen_US
dc.identifier.doihttp://dx.doi.org/10.1039/C4EE00957F
dc.description.versionPublished versionen_US


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