dc.contributor.authorYang, Peng
dc.contributor.authorXu, Haiyan
dc.contributor.authorZhou, Jianrong Steve
dc.date.accessioned2014-12-11T08:43:48Z
dc.date.available2014-12-11T08:43:48Z
dc.date.copyright2014en_US
dc.date.issued2014
dc.identifier.citationYang, P., Xu, H., & Zhou, J. S. (2014). Nickel-catalyzed asymmetric transfer hydrogenation of olefins for the synthesis of α- and β-amino acids. Angewandte chemie international edition, 53(45), 12210-12213.en_US
dc.identifier.issn1433-7851en_US
dc.identifier.urihttp://hdl.handle.net/10220/24444
dc.description.abstractThe field of asymmetric (transfer) hydrogenation of prochiral olefins has been dominated by noble metal catalysts based on rhodium, ruthenium, and iridium. Herein we report that a simple nickel catalyst is highly active in the transfer hydrogenation using formic acid. Chiral α- and β-amino acid derivatives were obtained in good to excellent enantioselectivity. The key toward success was the use of the strongly donating and sterically demanding bisphosphine Binapine.en_US
dc.language.isoenen_US
dc.relation.ispartofseriesAngewandte chemie international editionen_US
dc.rights© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en_US
dc.subjectDRNTU::Science::Chemistry::Physical chemistry::Catalysis
dc.titleNickel-catalyzed asymmetric transfer hydrogenation of olefins for the synthesis of α- and β-amino acidsen_US
dc.typeJournal Article
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doihttp://dx.doi.org/10.1002/anie.201407744


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