Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/103479
Title: Activation of a 1-chlorophosphirane complex by aluminum trichloride : generation and trapping of [Fc-P-W(CO)5] (Fc = Ferrocenyl)
Authors: Ho, Feny
Ganguly, Rakesh
Mathey, François
Keywords: DRNTU::Science::Chemistry::Inorganic chemistry
Issue Date: 2014
Source: Ho, F., Ganguly, R., & Mathey, F. (2014). Activation of a 1-chlorophosphirane complex by aluminum trichloride : generation and trapping of [Fc-P-W(CO)5] (Fc = Ferrocenyl). European journal of inorganic chemistry, 2014(28), 4726-4729.
Series/Report no.: European journal of inorganic chemistry
Abstract: Aluminum trichloride catalyzes the ring opening of a 1-chlorophosphirane W(CO)5 complex and its reaction with thiophene and ferrocene to give the corresponding 1-(2-thienyl)- and 1-ferrocenylphosphirane derivatives. The W(CO)5 complex of the 1-ferrocenylphosphirane is an efficient precursor of the phosphinidene complex [FcP-W(CO)5], which is trapped by tolan, trans-stilbene, and water.
URI: https://hdl.handle.net/10356/103479
http://hdl.handle.net/10220/24536
ISSN: 1434-1948
DOI: http://dx.doi.org/10.1002/ejic.201402662
Rights: © 2014 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
metadata.item.grantfulltext: none
metadata.item.fulltext: No Fulltext
Appears in Collections:SPMS Journal Articles

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