Asymmetric construction of a ferrocenyl phosphapalladacycle from achiral enones and a demonstration of its catalytic potential
Pullarkat, Sumod A.
Date of Issue2014
School of Physical and Mathematical Sciences
A new approach toward ferrocenyl phosphapalladacycle construction from achiral enones via asymmetric hydrophosphination and subsequent diastereoselective C–H activation is described. Its catalytic efficacy toward C–C bond formation is subsequently illustrated.
DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
© 2014 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Organometallics, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1021/om5007215].