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|Title:||Isolation of an imino-N-heterocyclic carbene/germanium(0) adduct : a mesoionic germylene equivalent||Authors:||Su, Bochao
|Keywords:||DRNTU::Science::Chemistry||Issue Date:||2014||Source:||Su, B., Ganguly, R., Li, Y., & Kinjo, R. (2014). Isolation of an imino-N-heterocyclic carbene/germanium(0) adduct : a mesoionic germylene equivalent. Angewandte chemie international edition, 53(48), 13106-13109.||Series/Report no.:||Angewandte chemie international edition||Abstract:||An autoionization of germanium dichloride/dioxane complex with an imino-N-heterocyclic carbene ligand (L) afforded a novel germyliumylidene ion, [(L)GeCl]+[GeCl3]−, which was fully characterized. Reduction of the germyliumylidene ion with potassium graphite produced a cyclic species [(L)Ge], which can be viewed as both a Ge0 species and a mesoionic germylene. X-ray diffraction analysis and computational studies revealed one of the lone pairs on the Ge atom is involved in the π system on the GeC2N2 five-membered ring. It was also confirmed that the nucleophilic behavior of [(L)Ge] as a two lone-pair donor.||URI:||https://hdl.handle.net/10356/103941
|ISSN:||1433-7851||DOI:||http://dx.doi.org/10.1002/anie.201406930||Rights:||© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.||Fulltext Permission:||none||Fulltext Availability:||No Fulltext|
|Appears in Collections:||SPMS Journal Articles|
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