dc.contributor.authorSu, Bochao
dc.contributor.authorGanguly, Rakesh
dc.contributor.authorLi, Yongxin
dc.contributor.authorKinjo, Rei
dc.date.accessioned2015-01-15T06:37:25Z
dc.date.available2015-01-15T06:37:25Z
dc.date.copyright2014en_US
dc.date.issued2014
dc.identifier.citationSu, B., Ganguly, R., Li, Y., & Kinjo, R. (2014). Isolation of an imino-N-heterocyclic carbene/germanium(0) adduct : a mesoionic germylene equivalent. Angewandte chemie international edition, 53(48), 13106-13109.en_US
dc.identifier.issn1433-7851en_US
dc.identifier.urihttp://hdl.handle.net/10220/24633
dc.description.abstractAn autoionization of germanium dichloride/dioxane complex with an imino-N-heterocyclic carbene ligand (L) afforded a novel germyliumylidene ion, [(L)GeCl]+[GeCl3]−, which was fully characterized. Reduction of the germyliumylidene ion with potassium graphite produced a cyclic species [(L)Ge], which can be viewed as both a Ge0 species and a mesoionic germylene. X-ray diffraction analysis and computational studies revealed one of the lone pairs on the Ge atom is involved in the π system on the GeC2N2 five-membered ring. It was also confirmed that the nucleophilic behavior of [(L)Ge] as a two lone-pair donor.en_US
dc.language.isoenen_US
dc.relation.ispartofseriesAngewandte chemie international editionen_US
dc.rights© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en_US
dc.subjectDRNTU::Science::Chemistry
dc.titleIsolation of an imino-N-heterocyclic carbene/germanium(0) adduct : a mesoionic germylene equivalenten_US
dc.typeJournal Article
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doihttp://dx.doi.org/10.1002/anie.201406930


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