Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/103967
Title: Synthesis of annelated phospholes through intramolecular C-H activation by monovalent phosphorus
Authors: Wei, Xinda
Lu, Zongming
Zhao, Xu
Duan, Zheng
Mathey, Francois
Keywords: DRNTU::Science::Chemistry
Issue Date: 2015
Source: Wei, X., Lu, Z., Zhao, X., Duan, Z., & Mathey, F. (2015). Synthesis of annelated phospholes through intramolecular C-H activation by monovalent phosphorus. Angewandte chemie international edition, 54(5), 1583-1586.
Series/Report no.: Angewandte chemie international edition
Abstract: Electrophilic terminal phosphinidene complexes [Ar-Ar-P-W(CO)5] (Ar-Ar: biaryl or an analogue thereof) undergo a spontaneous insertion of the phosphorus atom into the vicinal C-H bonds to give annelated phospholes. Twelve examples are described, including biphenyl, thienyl, pyrrolyl, and benzofuryl groups as biaryl moieties. The activation energy of the insertion reaction is quite low (about 2 kcal mol−1).
URI: https://hdl.handle.net/10356/103967
http://hdl.handle.net/10220/24636
ISSN: 1433-7851
DOI: http://dx.doi.org/10.1002/anie.201410603
Rights: © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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