Mn(iii)-catalyzed radical reactions of 1,3-dicarbonyl compounds and cyclopropanols with vinyl azides for divergent synthesis of azaheterocycles
Date of Issue2012
School of Physical and Mathematical Sciences
Mn(iii)-catalyzed formal [3+2]- and [3+3]-annulations have been developed using readily available vinyl azides with 1,3-dicarbonyl compounds and cyclopropanols. Vinyl azides were successfully applied as a three-atom unit including one nitrogen to prepare various azaheterocycles via Mn(iii)-catalyzed radical reactions.
© 2012 Swiss Chemical Society. This paper was published in CHIMIA and is made available as an electronic reprint (preprint) with permission of Swiss Chemical Society. The paper can be found at the following official DOI: [http://dx.doi.org/10.2533/chimia.2012.377]. One print or electronic copy may be made for personal use only. Systematic or multiple reproduction, distribution to multiple locations via electronic or other means, duplication of any material in this paper for a fee or for commercial purposes, or modification of the content of the paper is prohibited and is subject to penalties under law.