dc.contributor.authorChew, Renta Jonathan
dc.contributor.authorLi, Xi-Rui
dc.contributor.authorLi, Yongxin
dc.contributor.authorPullarkat, Appukuttan Sumod
dc.contributor.authorLeung, Pak-Hing
dc.date.accessioned2015-03-09T03:12:16Z
dc.date.available2015-03-09T03:12:16Z
dc.date.copyright2015en_US
dc.date.issued2015
dc.identifier.citationChew, R. J., Li, X.-R., Li, Y., Pullarkat, S. A., & Leung, P.-H. (2015). Pd-catalyzed enantiodivergent and regiospecific phospha-michael addition of diphenylphosphine to 4-oxo-enamides : efficient access to chiral phosphinocarboxamides and their analogues. Chemistry - A European journal, 21(12), 4800-4804 .en_US
dc.identifier.issn0947-6539en_US
dc.identifier.urihttp://hdl.handle.net/10220/25190
dc.description.abstractThe palladacycle-catalyzed asymmetric P-H addition of 4-oxo-enamides has been developed, which provides efficient access to phosphinocarboxamides and their analogues. Solvent-mediated reversal of stereoselectivity (ee from +96 % to −92 %) was observed, and the underlying mechanism that allows facile access to both enantiomers of the product by judicious choice of solvents is revealed.en_US
dc.language.isoenen_US
dc.relation.ispartofseriesChemistry - A European journalen_US
dc.rights© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en_US
dc.subjectDRNTU::Science::Chemistry
dc.titlePd-catalyzed enantiodivergent and regiospecific phospha-michael addition of diphenylphosphine to 4-oxo-enamides : efficient access to chiral phosphinocarboxamides and their analoguesen_US
dc.typeJournal Article
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doihttp://dx.doi.org/10.1002/chem.201406298


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