dc.contributor.authorDu, Yu
dc.contributor.authorWang, Yuhuang
dc.contributor.authorLi, Xin
dc.contributor.authorShao, Yaling
dc.contributor.authorLi, Guohui
dc.contributor.authorWebster, Richard D.
dc.contributor.authorChi, Robin Yonggui
dc.date.accessioned2015-04-07T08:33:27Z
dc.date.available2015-04-07T08:33:27Z
dc.date.copyright2014en_US
dc.date.issued2014
dc.identifier.citationDu, Y., Wang, Y., Li, X., Shao, Y., Li, G., Webster, R. D., et al. (2014). N-heterocyclic carbene organocatalytic reductive β,β-coupling reactions of nitroalkenes via radical intermediates. Organic letters, 16(21), 5678-5681.en_US
dc.identifier.urihttp://hdl.handle.net/10220/25333
dc.description.abstractAn unprecedented N-heterocyclic carbene catalytic reductive β,β-carbon coupling of α,β-nitroalkenes, by using an organic substrate to mimic the one-electron oxidation role of the pyruvate ferredoxin oxidoreductase (PFOR) in living systems, has been developed. The reaction goes through a radical anion intermediate generated under a catalytic redox process. For the first time, the presence of radical anion intermediate in NHC organocatalysis is observed and clearly verified.en_US
dc.language.isoenen_US
dc.relation.ispartofseriesOrganic lettersen_US
dc.rights© 2014 American Chemical Society.en_US
dc.subjectDRNTU::Science::Chemistry::Organic chemistry
dc.titleN-heterocyclic carbene organocatalytic reductive β,β-coupling reactions of nitroalkenes via radical intermediatesen_US
dc.typeJournal Article
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doihttp://dx.doi.org/10.1021/ol5027415
dc.identifier.rims184169


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