dc.contributor.authorChan, Siu-Chung
dc.contributor.authorPat, Pak-Kei
dc.contributor.authorLau, Tai-Chu
dc.contributor.authorWong, Chun-Yuen
dc.date.accessioned2015-05-11T04:01:39Z
dc.date.available2015-05-11T04:01:39Z
dc.date.copyright2011en_US
dc.date.issued2011
dc.identifier.citationChan, S.-C., Pat, P.-K., Lau, T.-C., & Wong, S.-Y. (2011). Facile direct insertion of nitrosonium ion (NO+) into a ruthenium-aryl bond. Organometallics, 30(6), 1311-1314en_US
dc.identifier.urihttp://hdl.handle.net/10220/25490
dc.description.abstractAn insertion reaction of nitrosonium ion (NO+) into the metal−carbon bond of cyclometalated ruthenium(II) complexes is prepared with experimental evidence supporting a bimolecular direct NO+ insertion into the metal−carbon bond (i.e., M−R + NO+ → [M−N(═O)−R]+) but not an intramolecular migratory insertion (i.e., R−M−(NO) + L → L−M−N(═O)R) as the reaction mechanism. Theoretical calculations suggest that the direct NO+ insertion into the M−C bond may be rationalized as a frontier orbital interaction between the [Ru−aryl]-dominated HOMO of the Ru(II) complexes and the LUMO of the NO+.en_US
dc.format.extent4 p.en_US
dc.language.isoenen_US
dc.relation.ispartofseriesOrganometallicsen_US
dc.rights© 2011 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Organometallics, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1021/om200095v].en_US
dc.subjectDRNTU::Science::Physics
dc.titleFacile direct insertion of nitrosonium ion (NO+) into a ruthenium-aryl bonden_US
dc.typeJournal Article
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doihttp://dx.doi.org/10.1021/om200095v
dc.description.versionAccepted version
dc.identifier.rims185983


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