Palladium-catalyzed asymmetric reductive heck reaction of aryl halides
Zhou, Jianrong Steve
Date of Issue2015
School of Physical and Mathematical Sciences
Asymmetric reductive Heck reaction of aryl halides is realized in high stereoselectivity. Hydrogen-bond donors, trialkylammonium salts in a glycol solvent, were used to promote halide dissociation from neutral arylpalladium complexes to access cationic, stereoselective pathways.
Angewandte chemie International edition
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.