dc.contributor.authorPoh, Hwee Ling
dc.contributor.authorSofer, Zdeněk
dc.contributor.authorŠimek, Petr
dc.contributor.authorTomandl, Ivo
dc.contributor.authorPumera, Martin
dc.date.accessioned2015-05-20T02:59:03Z
dc.date.available2015-05-20T02:59:03Z
dc.date.copyright2015en_US
dc.date.issued2015
dc.identifier.citationPoh, H. L., Sofer, Z., Šimek, P., Tomandl, I., & Pumera, M. (2015). Hydroboration of graphene oxide : towards stoichiometric graphol and hydoroxygraphane. Chemistry - a European journal, 21(22), 8130-8136.en_US
dc.identifier.issn0947-6539en_US
dc.identifier.urihttp://hdl.handle.net/10220/25615
dc.description.abstractCovalently functionalized graphene materials with well-defined stoichiometric composition are of a very high importance in the research of 2D carbon material family due to their well-defined properties. Unfortunately, most of the contemporary graphene-functionalized materials do not have this kind of defined composition and, usually, the amount of heteroatoms bonded to graphene framework is in the range of 1–10 at. %. Herein, we show that by a well-established hydroboration reaction chain, which introduces ——BH2 groups into the graphene oxide structure, followed by H2O2 or CF3COOH treatment as source of ——OH or ——H, we can obtain highly hydroxylated compounds of precisely defined composition with a general formula (C1O0.78H0.75)n, which we named graphol and highly hydroxylated graphane (C1(OH)0.51H0.14)n, respectively. These highly functionalized materials with an accurately defined composition are highly important for the field of graphene derivatives. The enhanced electrochemical performance towards important biomarkers as well as hydrogen evolution reaction is demonstrated.en_US
dc.language.isoenen_US
dc.relation.ispartofseriesChemistry - a European journalen_US
dc.rights© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en_US
dc.subjectDRNTU::Science::Chemistry::Physical chemistry::Electrochemistry
dc.titleHydroboration of graphene oxide : towards stoichiometric graphol and hydoroxygraphaneen_US
dc.typeJournal Article
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doihttp://dx.doi.org/10.1002/chem.201406168


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