dc.contributor.authorSong, Xiaohui
dc.contributor.authorDing, Tao
dc.contributor.authorYao, Lin
dc.contributor.authorLin, Ming
dc.contributor.authorLee, Rachel Siew Tan
dc.contributor.authorLiu, Cuicui
dc.contributor.authorSokol, Katarzyna
dc.contributor.authorYu, Le
dc.contributor.authorLou, David Xiong Wen
dc.contributor.authorChen, Hongyu
dc.date.accessioned2015-06-23T08:06:47Z
dc.date.available2015-06-23T08:06:47Z
dc.date.copyright2015en_US
dc.date.issued2015
dc.identifier.citationSong, X., Ding, T., Yao, L., Lin, M., Lee, R. S. T., Liu, C., et al. (2015). On the origin and underappreciated effects of ion doping in silica. Small, 11(34), 4351-4365.en_US
dc.identifier.issn1613-6810en_US
dc.identifier.urihttp://hdl.handle.net/10220/26038
dc.description.abstractThe origin of selectivity in the hollowing of silica nanoparticles is investigated to further understand silica. It is realized that, during the synthesis, the silica precursors are essentially ion-paired polyelectrolytes, whose nucleation depends on the concentration of the counter ions, and most importantly, the size/length of the poly(silicic acid). Thus, the “silica” that nucleates out at the different stages of synthesis has different degrees of ion doping, which explains its solubility in water, its microporosity, and the selective etching phenomena. The etching of silica in water is shown to be a matter of silica solubility, which correlates to the relative amounts of solvent and to the solvent quality (the water/isopropanol ratio). Hollowing does not occur when the silica nanoparticles are incubated in solutions presaturated with “silica,” ruling out surface reposition and Ostwald ripening as the hollowing mechanism. The embedded ions in silica are confirmed by elemental analysis (CHNS) and inductively coupled plasma-mass spectrometry. The high ionic doping ratios (N/Si = 2.3% for NH3-catalyzed silica; Na/Si = 11.2% for NaOH-catalyzed silica) explain the unusual solubility of silica in neutral water. The new view of silica with the ionic impurities on the central stage allows for insights in silica properties and versatility in synthetic design.en_US
dc.description.sponsorshipASTAR (Agency for Sci., Tech. and Research, S’pore)en_US
dc.language.isoenen_US
dc.relation.ispartofseriesSmallen_US
dc.rights© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en_US
dc.subjectDRNTU::Engineering::Chemical engineering::Chemical processes
dc.titleOn the origin and underappreciated effects of ion doping in silicaen_US
dc.typeJournal Article
dc.contributor.schoolSchool of Chemical and Biomedical Engineeringen_US
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doihttp://dx.doi.org/10.1002/smll.201500539


Files in this item

FilesSizeFormatView

There are no files associated with this item.

This item appears in the following Collection(s)

Show simple item record