dc.contributor.authorLee, Siew Siang
dc.contributor.authorBai, Hongwei
dc.contributor.authorLiu, Zhaoyang
dc.contributor.authorSun, Darren Delai
dc.date.accessioned2015-07-14T08:30:18Z
dc.date.available2015-07-14T08:30:18Z
dc.date.copyright2015en_US
dc.date.issued2015
dc.identifier.citationLee, S. S., Bai, H., Liu, Z., & Sun, D. D. (2015). Green approach for photocatalytic Cu(II)-EDTA degradation over TiO2 : toward environmental sustainability. Environmental science & technology, 49(4), 2541-2548.en_US
dc.identifier.issn0013-936Xen_US
dc.identifier.urihttp://hdl.handle.net/10220/38328
dc.description.abstractA green approach was successfully developed to reap three environmental benefits simultaneously: (1) clean water production, (2) hydrogen (H2) generation, and (3) well-dispersed in situ Cu2+ recovery for direct TiO2–CuO composite reclamation, by exploiting the synergistic integration of photocatalytic reaction of Cu-EDTA and one-dimensional (1D) ultralong and ultrathin TiO2 nanofibers. In this light-initiated system, Cu-EDTA was oxidized by TiO2 thus releasing Cu2+ which was reduced and recovered through uniform adsorption onto the long and porous TiO2 surface. A win–win platform was thus attained, on which Cu was recovered while providing active sites for H2 generation via photoreduction of H2O and enhancing photo-oxidation of remaining intermediate oxidation byproducts. Experimental results showed a H2 generation rate of 251 μmol/h concomitantly with TOC reduction. The used TiO2 nanofibers deposited with Cu were reclaimed directly as the TiO2–CuO composite after a facile heat treatment without additional chemicals and subsequently reusable for photocatalytic treatment of other wastewater (glycerol) to cogenerate H2 and clean water under both UV–visible and visible light. This study expounds a significant advancement through an ingenious integration which enhances the environmental sustainability of Cu-EDTA treatment via TiO2 photocatalysis. It also represents a promising and adoptable approach to synthesize other functional composite nanomaterials in a green manner thus broadening its environmental application spectrum, as it promotes industrial environmental management via waste segregation and motivates research to recover more resources from wastewater.en_US
dc.description.sponsorshipNRF (Natl Research Foundation, S’pore)en_US
dc.format.extent29 p. + supplementary informationen_US
dc.language.isoenen_US
dc.relation.ispartofseriesEnvironmental science & technologyen_US
dc.rights© 2015 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Environmental Science & Technology, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1021/es504711e].en_US
dc.subjectDRNTU::Engineering::Environmental engineering::Water treatment
dc.titleGreen approach for photocatalytic Cu(II)-EDTA degradation over TiO2 : toward environmental sustainabilityen_US
dc.typeJournal Article
dc.contributor.schoolSchool of Civil and Environmental Engineeringen_US
dc.identifier.doihttp://dx.doi.org/10.1021/es504711e
dc.description.versionAccepted versionen_US
dc.contributor.organizationPublic Utilities Board (PUB)en_US
dc.contributor.organizationEnergy Research Instituteen_US


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