Please use this identifier to cite or link to this item:
|Title:||Controllable chemoselectivity in visible-light photoredox catalysis : four diverse aerobic radical cascade reactions||Authors:||Liu, Xinfei
|Keywords:||DRNTU::Science::Chemistry::Physical chemistry::Catalysis||Issue Date:||2015||Source:||Liu, X., Ye, X., Bureš, F., Liu, H., & Jiang, Z. (2015). Controllable chemoselectivity in visible-light photoredox catalysis : four diverse aerobic radical cascade reactions. Angewandte chemie international edition, 54(39), 11443-11447.||Series/Report no.:||Angewandte chemie international edition||Abstract:||Reported is the controllable selectivity syntheses of four distinct products from the same starting materials by visible-light photoredox catalysis. By employing a dicyanopyrazine-derived chromophore (DPZ) as photoredox catalyst, an aerobic radical mechanism has been developed, and allows the reactions of N-tetrahydroisoquinolines (THIQs) with N-itaconimides to through four different pathways, including addition-cyclization, addition-elimination, addition-coupling, and addition-protonation, with satisfactory chemoselectivity. The current strategy provide straightforward access to four different but valuable N-heterocyclic adducts in moderate to excellent yields.||URI:||https://hdl.handle.net/10356/97190
|ISSN:||1433-7851||DOI:||http://dx.doi.org/10.1002/anie.201505193||Rights:||© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.||Fulltext Permission:||none||Fulltext Availability:||No Fulltext|
|Appears in Collections:||SPMS Journal Articles|
Items in DR-NTU are protected by copyright, with all rights reserved, unless otherwise indicated.