Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/97190
Title: Controllable chemoselectivity in visible-light photoredox catalysis : four diverse aerobic radical cascade reactions
Authors: Liu, Xinfei
Ye, Xinyi
Bureš, Filip
Liu, Hongjun
Jiang, Zhiyong
Keywords: DRNTU::Science::Chemistry::Physical chemistry::Catalysis
Issue Date: 2015
Source: Liu, X., Ye, X., Bureš, F., Liu, H., & Jiang, Z. (2015). Controllable chemoselectivity in visible-light photoredox catalysis : four diverse aerobic radical cascade reactions. Angewandte chemie international edition, 54(39), 11443-11447.
Series/Report no.: Angewandte chemie international edition
Abstract: Reported is the controllable selectivity syntheses of four distinct products from the same starting materials by visible-light photoredox catalysis. By employing a dicyanopyrazine-derived chromophore (DPZ) as photoredox catalyst, an aerobic radical mechanism has been developed, and allows the reactions of N-tetrahydroisoquinolines (THIQs) with N-itaconimides to through four different pathways, including addition-cyclization, addition-elimination, addition-coupling, and addition-protonation, with satisfactory chemoselectivity. The current strategy provide straightforward access to four different but valuable N-heterocyclic adducts in moderate to excellent yields.
URI: https://hdl.handle.net/10356/97190
http://hdl.handle.net/10220/38513
ISSN: 1433-7851
DOI: http://dx.doi.org/10.1002/anie.201505193
Rights: © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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