Tf 2 NH-catalyzed amide synthesis from vinyl azides and alcohols
Date of Issue2015
School of Physical and Mathematical Sciences
Triflimide (Tf2NH) specifically catalyzed reactions of alcohols and vinyl azides, enabling efficient construction of amides with C–C bond formation through nucleophilic attack of vinyl azides onto the putative carbocation intermediates derived from alcohols are described.
© 2015 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Organic Letters, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1021/acs.orglett.5b01458].