Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/103522
Title: Iminoiodane- and Brønsted Base-Mediated Cross Dehydrogenative Coupling of Cyclic Ethers with 1,3-Dicarbonyl Compounds
Authors: Chan, Philip Wai Hong
Tejo, Ciputra
Sim, Xiao Rong
Lee, Bo Ra
Ayers, Benjamin James
Leung, Chung-Hang
Ma, Dik-Lung
Issue Date: 2015
Source: Tejo, C., Sim, X., Lee, B., Ayers, B., Leung, C. H., Ma, D. L., et al. (2015). Iminoiodane- and Brønsted Base-Mediated Cross Dehydrogenative Coupling of Cyclic Ethers with 1,3-Dicarbonyl Compounds. Molecules, 20(7), 13336-13353.
Series/Report no.: Molecules
Abstract: A one-pot, two-step approach to prepare 2-tetrahydrofuran and -pyran substituted 1,3-dicarbonyl compounds by PhI=NTs-mediated amination/Brønsted base-catalyzed cross dehydrogenative coupling (CDC) reaction of the cyclic ether and 1,3-dicarbonyl derivative under mild conditions is reported. The reaction is compatible with a variety of cyclic ethers and 1,3-dicarbonyl compounds, affording the corresponding coupled products in moderate to good yields of up to 80% over two steps.
URI: https://hdl.handle.net/10356/103522
http://hdl.handle.net/10220/38771
ISSN: 1420-3049
DOI: 10.3390/molecules200713336
Rights: © 2015 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/4.0/).
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

Google ScholarTM

Check

Altmetric


Plumx

Items in DR-NTU are protected by copyright, with all rights reserved, unless otherwise indicated.