Anti-Markovnikov hydroimination of terminal alkynes in gold-catalyzed pyridine construction from ammonia
Date of Issue2015
School of Physical and Mathematical Sciences
NTU-CBC Crystallography Facility
Gold-catalyzed hydroimination of terminal alkynes, giving rise to anti-Markovnikov adducts concomitant with unstable Markovnikov adducts is described. The elementary step can be applied for the construction of pyridine derivatives from ammonia and alkynes.
Gold-catalyzed; hydroimination; ammonia; alkynes
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