dc.contributor.authorGe, Jingjie
dc.contributor.authorHe, Dongsheng
dc.contributor.authorBai, Lei
dc.contributor.authorYou, Rui
dc.contributor.authorLu, Haiyuan
dc.contributor.authorLin, Yue
dc.contributor.authorTan, Chaoliang
dc.contributor.authorKang, Yan-Biao
dc.contributor.authorXiao, Bin
dc.contributor.authorWu, Yuen
dc.contributor.authorDeng, Zhaoxiang
dc.contributor.authorHuang, Weixin
dc.contributor.authorZhang, Hua
dc.contributor.authorHong, Xun
dc.contributor.authorLi, Yadong
dc.date.accessioned2016-01-06T02:15:13Z
dc.date.available2016-01-06T02:15:13Z
dc.date.issued2015
dc.identifier.citationGe, J., He, D., Bai, L., You, R., Lu, H., Lin, Y., et al. (2015). Ordered Porous Pd Octahedra Covered with Monolayer Ru Atoms. Journal of the American Chemical Society, 137(46), 14566-14569.en_US
dc.identifier.issn0002-7863en_US
dc.identifier.urihttp://hdl.handle.net/10220/39578
dc.description.abstractMonolayer Ru atoms covered highly ordered porous Pd octahedra have been synthesized via the underpotential deposition and thermodynamic control. Shape evolution from concave nanocube to octahedron with six hollow cavities was observed. Using aberration-corrected high-resolution transmission electron microscopy and X-ray photoelectron spectroscopy, we provide quantitative evidence to prove that only a monolayer of Ru atoms was deposited on the surface of porous Pd octahedra. The as-prepared monolayer Ru atoms covered Pd nanostructures exhibited excellent catalytic property in terms of semihydrogenation of alkynes.en_US
dc.description.sponsorshipMOE (Min. of Education, S’pore)en_US
dc.format.extent4 p.en_US
dc.language.isoenen_US
dc.relation.ispartofseriesJournal of the American Chemical Societyen_US
dc.rights© 2015 American Chemical Society. This paper was published in Journal of the American Chemical Society and is made available as an electronic reprint (preprint) with permission of American Chemical Society. The published version is available at: [http://dx.doi.org/10.1021/jacs.5b08956]. One print or electronic copy may be made for personal use only. Systematic or multiple reproduction, distribution to multiple locations via electronic or other means, duplication of any material in this paper for a fee or for commercial purposes, or modification of the content of the paper is prohibited and is subject to penalties under law.en_US
dc.subjectMaterials Science and Engineering
dc.subjectHollow cavities
dc.subjectalkyne
dc.titleOrdered Porous Pd Octahedra Covered with Monolayer Ru Atomsen_US
dc.typeJournal Article
dc.contributor.schoolSchool of Materials Science and Engineeringen_US
dc.identifier.doihttp://dx.doi.org/10.1021/jacs.5b08956
dc.description.versionPublished versionen_US


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