dc.contributor.authorLei, Chuanhu
dc.contributor.authorJin, Xiaojia
dc.contributor.authorZhou, Jianrong (Steve)
dc.date.accessioned2016-05-10T07:25:46Z
dc.date.available2016-05-10T07:25:46Z
dc.date.copyright2015
dc.date.issued2015
dc.identifier.citationLei, C., Jin, X., & Zhou, J. (2015). Palladium-Catalyzed Heteroarylation and Concomitant ortho-Alkylation of Aryl Iodides. Angewandte Chemie International Edition, 54(45), 13397-13400.en_US
dc.identifier.issn1433-7851en_US
dc.identifier.urihttp://hdl.handle.net/10220/40514
dc.description.abstractThree-component couplings were achieved from common aryl halides, alkyl halides, and heteroarenes under palladium and norbornene co-catalysis. The reaction forges hindered aryl–heteroaryl bonds and introduces ortho-alkyl groups to aryl rings. Various heterocycles such as oxazoles, thiazoles and thiophenes underwent efficient coupling. The heteroarenes were deprotonated in situ by bases without the assistance of palladium catalysts.en_US
dc.description.sponsorshipMOE (Min. of Education, S’pore)en_US
dc.format.extent4 p.en_US
dc.language.isoenen_US
dc.relation.ispartofseriesAngewandte Chemie International Editionen_US
dc.rights© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en_US
dc.subjectcross-couplingen_US
dc.subjectheterocyclesen_US
dc.subjectpalladiumen_US
dc.subjectC-H activationen_US
dc.subjectsynthetic methoden_US
dc.titlePalladium-Catalyzed Heteroarylation and Concomitant ortho-Alkylation of Aryl Iodidesen_US
dc.typeJournal Article
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doihttp://dx.doi.org/10.1002/anie.201507128
dc.identifier.rims191130


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