dc.contributor.authorCai, Guofa
dc.contributor.authorDarmawan, Peter
dc.contributor.authorCui, Mengqi
dc.contributor.authorWang, Jiangxin
dc.contributor.authorChen, Jingwei
dc.contributor.authorMagdassi, Shlomo
dc.contributor.authorLee, Pooi See
dc.date.accessioned2016-06-02T01:25:11Z
dc.date.available2016-06-02T01:25:11Z
dc.date.copyright2015
dc.date.issued2015
dc.identifier.citationCai, G., Darmawan, P., Cui, M., Wang, J., Chen, J., Magdassi, S., et al. (2016). Highly Stable Transparent Conductive Silver Grid/PEDOT:PSS Electrodes for Integrated Bifunctional Flexible Electrochromic Supercapacitors. Advanced Energy Materials, 6, 1501882-.en_US
dc.identifier.issn1614-6832en_US
dc.identifier.urihttp://hdl.handle.net/10220/40597
dc.description.abstractSilver grids are attractive for replacing indium tin oxide as flexible transparent conductors. This work aims to improve the electrochemical stability of silver-based transparent conductors. A silver grid/PEDOT:PSS hybrid film with high conductivity and excellent stability is successfully fabricated. Its functionality for flexible electrochromic applications is demonstrated by coating one layer of WO3 nanoparticles on the silver grid/PEDOT:PSS hybrid film. This hybrid structure presents a large optical modulation of 81.9% at 633 nm, fast switching, and high coloration efficiency (124.5 cm2 C−1). More importantly, an excellent electrochemical cycling stability (sustaining 79.1% of their initial transmittance modulation after 1000 cycles) and remarkable mechanical flexibility (optical modulation decay of only 7.5% after 1200 compressive bending cycles) is achieved. A novel smart supercapacitor is presented that functions as a regular energy-storage device and simultaneously monitors the level of stored energy by a rapid and reversible color variation even at high current charge/discharge conditions. The film sustains an optical modulation of 87.7% and a specific capacitance of 67.2% at 10 A g−1 compared to their initial value at a current density of 1 A g−1. The high-performance silver grid/PEDOT:PSS hybrid transparent films exhibit promising features for various emerging flexible electronics and optoelectronic devices.en_US
dc.description.sponsorshipNRF (Natl Research Foundation, S’pore)en_US
dc.language.isoenen_US
dc.relation.ispartofseriesAdvanced Energy Materialsen_US
dc.rights© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This is the author created version of a work that has been peer reviewed and accepted for publication by Advanced Energy Materials, WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1002/aenm.201501882].en_US
dc.subjectsupercapacitorsen_US
dc.subjectflexible electrodesen_US
dc.subjecttransparent electrodesen_US
dc.subjectenergy storageen_US
dc.subjectsilver gridsen_US
dc.titleHighly Stable Transparent Conductive Silver Grid/PEDOT:PSS Electrodes for Integrated Bifunctional Flexible Electrochromic Supercapacitorsen_US
dc.typeJournal Article
dc.contributor.schoolSchool of Materials Science and Engineeringen_US
dc.identifier.doihttp://dx.doi.org/10.1002/aenm.201501882
dc.description.versionAccepted version
dc.identifier.rims192885


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