dc.contributor.authorZhang, Yuexia
dc.contributor.authorDu, Yu
dc.contributor.authorHuang, Zhijian
dc.contributor.authorXu, Jianfeng
dc.contributor.authorWu, Xingxing
dc.contributor.authorWang, Yuhuang
dc.contributor.authorWang, Ming
dc.contributor.authorYang, Song
dc.contributor.authorWebster, Richard D.
dc.contributor.authorChi, Robin Yonggui
dc.date.accessioned2016-06-07T05:59:29Z
dc.date.available2016-06-07T05:59:29Z
dc.date.copyright2015
dc.date.issued2015
dc.identifier.citationZhang, Y., Du, Y., Huang, Z., Xu, J., Wu, X., Wang, Y., et al. (2015). N-Heterocyclic Carbene-Catalyzed Radical Reactions for Highly Enantioselective β-Hydroxylation of Enals. Journal of the American Chemical Society, 137(7), 2416-2419.en_US
dc.identifier.issn0002-7863en_US
dc.identifier.urihttp://hdl.handle.net/10220/40626
dc.description.abstractAn N-heterocyclic carbene-catalyzed β-hydroxylation of enals is developed. The reaction goes through a pathway involving multiple radical intermediates, as supported by experimental observations. This oxidative single-electron-transfer reaction allows for highly enantioselective access to β-hydroxyl esters that are widely found in natural products and bioactive molecules.en_US
dc.description.sponsorshipNRF (Natl Research Foundation, S’pore)en_US
dc.format.extent4 p.en_US
dc.language.isoenen_US
dc.relation.ispartofseriesJournal of the American Chemical Societyen_US
dc.rights© 2015 American Chemical Society (ACS).en_US
dc.subjectChemistry and Biological Chemistryen_US
dc.titleN‑Heterocyclic Carbene-Catalyzed Radical Reactions for Highly Enantioselective β‑Hydroxylation of Enalsen_US
dc.typeJournal Article
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doihttp://dx.doi.org/10.1021/ja511371a
dc.identifier.rims184173


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