dc.contributor.authorTnay, Ya Lin
dc.contributor.authorAng, Gim Yean
dc.contributor.authorChiba, Shunsuke
dc.date.accessioned2016-06-28T08:59:03Z
dc.date.available2016-06-28T08:59:03Z
dc.date.issued2015
dc.identifier.citationTnay, Y. L., Ang, G. Y., & Chiba, S. (2015). Copper-catalyzed aerobic radical C-C bond cleavage of N-H ketimines. Beilstein Journal of Organic Chemistry, 11, 1933-1943.en_US
dc.identifier.issn1860-5397en_US
dc.identifier.urihttp://hdl.handle.net/10220/40822
dc.description.abstractWe report herein studies on copper-catalyzed aerobic radical C-C bond cleavage of N-H ketimines. Treatment of N-H ketimines having an alpha-sp3 hybridized carbon under Cu-catalyzed aerobic reaction conditions resulted in a radical fragmentation with C-C bond cleavage to give the corresponding carbonitrile and carbon radical intermediate. This radical process has been applied for the construction of oxaspirocyclohexadienones as well as in the electrophilic cyanation of Grignard reagents with pivalonitrile as a CN source.en_US
dc.format.extent11 p.en_US
dc.language.isoenen_US
dc.relation.ispartofseriesBeilstein Journal of Organic Chemistryen_US
dc.rights© 2015 The Author(s) (Published by Beilstein-Institut). This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.en_US
dc.subjectC-C bond cleavageen_US
dc.subjectcopperen_US
dc.subjectketiminesen_US
dc.subjectmolecular oxygenen_US
dc.subjectradicalen_US
dc.titleCopper-catalyzed aerobic radical C-C bond cleavage of N-H ketiminesen_US
dc.typeJournal Article
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doihttp://dx.doi.org/10.3762/bjoc.11.209
dc.description.versionPublished versionen_US


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