dc.contributor.authorMu, Chenzhong
dc.contributor.authorZhang, Liying
dc.contributor.authorSong, Yujie
dc.contributor.authorChen, Xuelong
dc.contributor.authorLiu, Ming
dc.contributor.authorWang, Fuke
dc.contributor.authorHu, Xiao
dc.date.accessioned2017-05-12T08:06:58Z
dc.date.available2017-05-12T08:06:58Z
dc.date.copyright2016
dc.date.issued2016
dc.identifier.citationMu, C., Zhang, L., Song, Y., Chen, X., Liu, M., Wang, F., et al. (2016). Modification of carbon nanotubes by a novel biomimetic approach towards the enhancement of the mechanical properties of polyurethane. Polymer, 92, 231-238.en_US
dc.identifier.issn0032-3861en_US
dc.identifier.urihttp://hdl.handle.net/10220/42398
dc.description23 p.
dc.description.abstractPolyurethane (PU) nanocomposites incorporated with polydopamine treated carbon nanotubes (PDA-CNTs) were prepared by solution casting method via in-situ polymerization, achieving excellent CNTs dispersion in the PU matrix. It was observed that, with a loading of only 0.3 wt%, the tensile modulus and tensile strength were increased by 40% and 100% respectively. This reinforcement even exceeded the predicted modulus by Halpin–Tsai model. It indicates extremely enhanced interfacial interaction between the fillers and the matrix. More interestingly, it was found that the incorporation of PDA-CNTs caused a significant change in the degree of phase separation in the PU matrix leading to a unique network-like structure which is responsible for the unexpected reinforcement effect. This understanding combining with the synthetic approach should be useful for future design of PU/CNTs nanocomposites for wide range of applications.en_US
dc.description.sponsorshipASTAR (Agency for Sci., Tech. and Research, S’pore)en_US
dc.format.extent8 p.en_US
dc.language.isoenen_US
dc.relation.ispartofseriesPolymeren_US
dc.rights© 2016 Elsevier Ltd. This is the author created version of a work that has been peer reviewed and accepted for publication by Polymer, Elsevier. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [https://doi.org/10.1016/j.polymer.2016.03.085].en_US
dc.subjectCarbon nanotubesen_US
dc.subjectInterfaceen_US
dc.titleModification of carbon nanotubes by a novel biomimetic approach towards the enhancement of the mechanical properties of polyurethaneen_US
dc.typeJournal Article
dc.contributor.researchEnergy Research Institute @NTUen_US
dc.contributor.researchTemasek Laboratoriesen_US
dc.contributor.schoolSchool of Materials Science and Engineeringen_US
dc.identifier.doihttps://doi.org/10.1016/j.polymer.2016.03.085
dc.description.versionAccepted Version
dc.identifier.rims191530


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