dc.contributor.authorLeow, Wan Ru
dc.contributor.authorNg, Wilson Kwok Hung
dc.contributor.authorPeng, Tai
dc.contributor.authorLiu, Xinfeng
dc.contributor.authorLi, Bin
dc.contributor.authorShi, Wenxiong
dc.contributor.authorLum, Yanwei
dc.contributor.authorWang, Xiaotian
dc.contributor.authorLang, Xianjun
dc.contributor.authorLi, Shuzhou
dc.contributor.authorMathews, Nripan
dc.contributor.authorAger, Joel W.
dc.contributor.authorSum, Tze Chien
dc.contributor.authorHirao, Hajime
dc.contributor.authorChen, Xiaodong
dc.date.accessioned2017-05-30T02:04:32Z
dc.date.available2017-05-30T02:04:32Z
dc.date.copyright2016
dc.date.issued2016
dc.identifier.citationLeow, W. R., Ng, W. K. H., Peng, T., Liu, X., Li, B., Shi, W., et al. (2017). Al2O3 Surface Complexation for Photocatalytic Organic Transformations. Journal of the American Chemical Society, 139(1), 269-276.en_US
dc.identifier.issn0002-7863en_US
dc.identifier.urihttp://hdl.handle.net/10220/42517
dc.description.abstractThe use of sunlight to drive organic reactions constitutes a green and sustainable strategy for organic synthesis. Herein, we discovered that the earth-abundant aluminum oxide (Al2O3) though paradigmatically known to be an insulator could induce an immense increase in the selective photo-oxidation of different benzyl alcohols in the presence of a large variety of dyes and O2. This unique phenomenon is based on the surface complexation of benzyl alcohol (BnOH) with the Brønsted base sites on Al2O3, which reduces its oxidation potential and causes an upshift in its HOMO for electron abstraction by the dye. The surface complexation of O2 with Al2O3 also activates the adsorbed O2 for receiving electrons from the photoexcited dyes. This discovery brings forth a new understanding on utilizing surface complexation mechanisms between the reactants and earth abundant materials to effectively achieve a wider range of photoredox reactions.en_US
dc.description.sponsorshipNRF (Natl Research Foundation, S’pore)en_US
dc.description.sponsorshipMOE (Min. of Education, S’pore)en_US
dc.language.isoenen_US
dc.relation.ispartofseriesJournal of the American Chemical Societyen_US
dc.rights© 2016 American Chemical Societyen_US
dc.titleAl2O3 Surface Complexation for Photocatalytic Organic Transformationsen_US
dc.typeJournal Article
dc.contributor.schoolSchool of Materials Science and Engineeringen_US
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doihttp://dx.doi.org/10.1021/jacs.6b09934
dc.identifier.rims201160


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