dc.contributor.authorZhang, Yuexia
dc.contributor.authorWong, Zeng Rong
dc.contributor.authorWu, Xingxing
dc.contributor.authorLauw, Sherman Jun Liang
dc.contributor.authorHuang, Xuan
dc.contributor.authorWebster, Richard David
dc.contributor.authorChi, Yonggui Robin
dc.date.accessioned2017-07-31T03:20:12Z
dc.date.available2017-07-31T03:20:12Z
dc.date.issued2017
dc.identifier.citationZhang, Y., Wong, Z. R., Wu, X., Lauw, S. J. L., Huang, X., Webster, R. D., et al. (2017). Sulfoxidation of alkenes and alkynes with NFSI as a radical initiator and selective oxidant. Chemical Communications, 53(1), 184-187.en_US
dc.identifier.issn1359-7345en_US
dc.identifier.urihttp://hdl.handle.net/10220/43495
dc.description.abstractSulfoxides are important functional molecules. We develop a short-route (one-pot) synthesis of this class of molecules by reacting thiols with alkenes or alkynes under mild and metal-free conditions. N-Fluorobenzenesulfonimide (NFSI) is used to play dual roles: as a radical initiator for a thiol–ene/–yne reaction to form sulfide adducts, and as efficient oxidant for conversion of the sulfides formed in situ to sulfoxides. Over-oxidation of the sulfoxides to sulfones is avoided in our approach.en_US
dc.description.sponsorshipNRF (Natl Research Foundation, S’pore)en_US
dc.description.sponsorshipMOE (Min. of Education, S’pore)en_US
dc.format.extent4 p.en_US
dc.language.isoenen_US
dc.relation.ispartofseriesChemical Communicationsen_US
dc.rights© 2017 The Royal Society of Chemistry. This is the author created version of a work that has been peer reviewed and accepted for publication by Chemical Communications, The Royal Society of Chemistry. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1039/C6CC08631D].en_US
dc.subjectSulfoxidesen_US
dc.subjectN-Fluorobenzenesulfonimideen_US
dc.titleSulfoxidation of alkenes and alkynes with NFSI as a radical initiator and selective oxidanten_US
dc.typeJournal Article
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doihttp://dx.doi.org/10.1039/C6CC08631D
dc.description.versionAccepted versionen_US


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