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Title: Palladium-Catalyzed Asymmetric α-Arylation of Alkylnitriles
Authors: Jiao, Zhiwei
Chee, Kwok Wei
Zhou, Jianrong Steve
Keywords: Palladium catalysis
Issue Date: 2016
Source: Jiao, Z., Chee, K. W., & Zhou, J. S. (2016). Palladium-Catalyzed Asymmetric α-Arylation of Alkylnitriles. Journal of the American Chemical Society, 138(50), 16240-16243.
Series/Report no.: Journal of the American Chemical Society
Abstract: Asymmetric arylation of alkylnitriles forms quaternary stereocenters in good enantiocontrol for the first time. A lithium heterodimer consisting of an alkylnitrile anion and a disilylamide ion is the actual species responsible for the stereodetermining transmetalation in the catalytic cycle.
ISSN: 0002-7863
Rights: © 2016 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Journal of the American Chemical Society, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [].
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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