dc.contributor.authorSun, Shengnan
dc.contributor.authorSun, Libo
dc.contributor.authorXi, Shibo
dc.contributor.authorDu, Yonghua
dc.contributor.authorAnu Prathap, M.U.
dc.contributor.authorWang, Zilong
dc.contributor.authorZhang, Qichun
dc.contributor.authorFisher, Adrian
dc.contributor.authorXu, Zhichuan Jason
dc.date.accessioned2017-09-18T03:08:44Z
dc.date.available2017-09-18T03:08:44Z
dc.date.issued2017
dc.identifier.citationSun, S., Sun, L., Xi, S., Du, Y., Anu Prathap, M. U., Wang, Z., et al. (2017). Electrochemical oxidation of C3 saturated alcohols on Co3O4 in alkaline. Electrochimica Acta, 228, 183-194.en_US
dc.identifier.issn0013-4686en_US
dc.identifier.urihttp://hdl.handle.net/10220/43750
dc.description.abstractIn this work, we present a systematic study on the electrochemical oxidation of C3 saturated alcohols (propanetriol, 1,2-propanediol, 1,3-propanediol, 1-propanol, and 2-propanol) on Co3O4 in alkaline. Co3O4 electrode was prepared by electrodeposition of Co(OH)2 on graphite paper followed with a calcination step. The electro-oxidation of C3 saturated alcohols were investigated by a combination of cyclic voltammetry, multi-step chronoamperometry, and electrochemical impedance spectroscopy techniques in KOH solution. The electro-oxidation studies at Co3O4 electrode followed an activity trend in the following order: propanetriol (GLY) > 1,2-propanediol (1,2-P) > 1,3-propanediol (1,3-P) > 1-propanol (1-P) > 2-propanol (2-P). The NMR analysis of the oxidized products showed that C-C bond cleavage occurred faster in alcohols having adjacent hydroxyl groups. X-ray absorption near-edge structure (XANES) spectroscopy study showed that there was no significant difference in Co oxidation state in the absence and the presence of glycerol. It was also found that the KOH concentration influenced electro-oxidation of those alcohols bearing secondary hydroxyl group (GLY, 1,2-P, and 2-P) more dramatically than that of those primary alcohols (1.3-P and 1-P).en_US
dc.description.sponsorshipNRF (Natl Research Foundation, S’pore)en_US
dc.description.sponsorshipMOE (Min. of Education, S’pore)en_US
dc.language.isoenen_US
dc.relation.ispartofseriesElectrochimica Actaen_US
dc.rights© 2017 Elsevier Ltd.en_US
dc.subjectCo3O4en_US
dc.subjectC3 Saturated Alcoholen_US
dc.titleElectrochemical oxidation of C3 saturated alcohols on Co3O4 in alkalineen_US
dc.typeJournal Article
dc.contributor.researchEnergy Research Institute @NTUen_US
dc.contributor.schoolSchool of Materials Science and Engineeringen_US
dc.identifier.doihttp://dx.doi.org/10.1016/j.electacta.2017.01.086


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