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      Templated formation of porous Mn2O3 octahedra from Mn-MIL-100 for lithium-ion battery anode materials

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      Author
      Zhang, Bowei
      Hao, Shiji
      Xiao, Dongrong
      Wu, Junsheng
      Huang, Yizhong
      Date of Issue
      2016
      School
      School of Materials Science and Engineering
      Interdisciplinary Graduate School
      Abstract
      Octahedral Mn-MIL-100 metal-organic frameworks (MOFs) are first synthesized, which are then used as templates to fabricate the porous Mn2O3 octahedra through a post-calcination strategy. The morphologies and crystalline structures of as-prepared Mn2O3 octahedra are performed by using field-emission scanning electron microscopy (FESEM), X-ray diffraction (XRD) and transmission electron microscopy (TEM). A reversible lithium storage capacity as high as 755 mA h/g at 0.2 C after 100 cycles is measured from Lithium-ion batteries (LIBs) where the porous Mn2O3 octahedra are acted as anode. Such a high performance indicates that the porous Mn2O3 structure is an excellent anode candidate of LIBs with high capacity and long-life cycling stability.
      Subject
      Porous Octahedra
      Manganese (III) Oxide
      Type
      Journal Article
      Series/Journal Title
      Materials and Design
      Rights
      © 2016 Elsevier Ltd.
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      • MSE Journal Articles
      http://dx.doi.org/10.1016/j.matdes.2016.03.041
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