Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/88350
Title: A room-temperature refuelable lithium, iodine and air battery
Authors: Tan, Kim Seng
Grimsdale, Andrew Clive
Yazami, Rachid
Keywords: Refuelable
Lithium-air
Issue Date: 2017
Source: Tan, K. S., Grimsdale, A. C., & Yazami, R. (2017). A room-temperature refuelable lithium, iodine and air battery. Scientific Reports, 7(1), 6502-.
Series/Report no.: Scientific Reports
Abstract: We demonstrate a new refuelable lithium cell using lithium solvated electron solution (Li-SES) as anolyte and iodine solutions as catholyte. This cell shows a high OCV (~3 V). Unlike conventional rechargeable Li batteries, this kind of cell can be re-fueled in several minutes by replacing the spent liquids. We also show for the first time, that Li-SES/I2 cells which operate at room temperature, can be prepared in a fully discharged state (~0 V OCV) for safe handling, transportation and storage. Li-SES and iodine are then electrochemically generated during charge as is confirmed by UV-VIS and a qualitative test. We have also conducted proof-of-concept tests for an “indirect lithium-air” cell in which iodine is reduced at the cathode and subsequently is catalytically re-oxidized by oxygen dissolved in the catholyte.
URI: https://hdl.handle.net/10356/88350
http://hdl.handle.net/10220/44597
ISSN: 2045-2322
DOI: http://dx.doi.org/10.1038/s41598-017-06321-w
Rights: © 2017 The Author(s) (Nature Publishing Group). This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. Te images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:ERI@N Journal Articles
MSE Journal Articles

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