dc.contributor.authorChin, Xin Yu
dc.contributor.authorPerumal, Ajay
dc.contributor.authorBruno, Annalisa
dc.contributor.authorYantara, Natalia
dc.contributor.authorVeldhuis, Sjoerd Antonius
dc.contributor.authorMartinez-Sarti, Laura
dc.contributor.authorChandran, Bevita
dc.contributor.authorChirvony, Vladimir S.
dc.contributor.authorLo, Alencious Shu-Zee
dc.contributor.authorSo, Jinkyu
dc.contributor.authorSoci, Cesare
dc.contributor.authorGrätzel, Michael
dc.contributor.authorBolink, Henk J.
dc.contributor.authorMathews, Nripan
dc.contributor.authorMhaisalkar, Subodh Gautam
dc.date.accessioned2018-03-23T02:32:33Z
dc.date.available2018-03-23T02:32:33Z
dc.date.copyright2018
dc.date.issued2018
dc.identifier.citationChin, X. Y., Perumal, A., Bruno, A., Yantara, N., Veldhuis, S. A., & Martínez‐Sarti, L., et al. (2018). Self-assembled hierarchical nanostructured perovskites enable highly efficient LEDs via an energy cascade. Energy & Environmental Science, in press.en_US
dc.identifier.issn1754-5692en_US
dc.identifier.urihttp://hdl.handle.net/10220/44602
dc.description.abstractMetal halide perovskites have established themselves as extraordinary optoelectronic materials, exhibiting promise for applications in large area illumination and displays. However, low luminescence, low efficiencies of the light-emitting diodes (LEDs), and complex preparation methods currently limit further progress towards applications. Here, we report on a new and unique mesoscopic film architecture featuring the self-assembly of 3D formamidinium lead bromide (FAPbBr3) nanocrystals of graded size, coupled with microplatelets of octylammonium lead bromide perovskites that enables an energy cascade, yielding very high-performance light-emitting diodes with emission in the green spectral region. These hierarchically structured perovskite films exhibit photoluminescence quantum yields of over 80% and LEDs associated with record high efficiencies in excess of 57.6 cd A−1 with an external quantum efficiency above 13%. Additionally, due to low turn-on voltages (~2.2 V) the LEDs have power efficiencies exceeding 58 lumens per Watt, obtained without any light-outcoupling structures.en_US
dc.description.sponsorshipNRF (Natl Research Foundation, S’pore)en_US
dc.description.sponsorshipMOE (Min. of Education, S’pore)en_US
dc.format.extent9 p.en_US
dc.language.isoenen_US
dc.relation.ispartofseriesEnergy & Environmental Scienceen_US
dc.rights© 2018 The Royal Society of Chemistry. This is the author created version of a work that has been peer reviewed and accepted for publication by Energy & Environmental Science, The Royal Society of Chemistry. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1039/C8EE00293B].en_US
dc.subjectEnergy Cascadeen_US
dc.subjectPerovskitesen_US
dc.titleSelf-assembled hierarchical nanostructured perovskites enable highly efficient LEDs via an energy cascadeen_US
dc.typeJournal Article
dc.contributor.researchEnergy Research Institute @NTUen_US
dc.contributor.schoolSchool of Materials Science and Engineeringen_US
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doihttp://dx.doi.org/10.1039/C8EE00293B
dc.description.versionAccepted versionen_US
dc.contributor.organizationCentre of Disruptive Photonics Technologiesen_US
dc.identifier.rims203652


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