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|Title:||Giant five-photon absorption from multidimensional core-shell halide perovskite colloidal nanocrystals||Authors:||Chen, Weiqiang
Veldhuis, Sjoerd A.
Sum, Tze Chien
|Issue Date:||2017||Source:||Chen, W., Bhaumik, S., Veldhuis, S. A., Xing, G., Xu, Q., Grätzel, M., et al. (2017). Giant five-photon absorption from multidimensional core-shell halide perovskite colloidal nanocrystals. Nature Communications, 8, 15198-.||Series/Report no.:||Nature Communications||Abstract:||Multiphoton absorption processes enable many technologically important applications, such as in vivo imaging, photodynamic therapy and optical limiting, and so on. Specifically, higher-order nonlinear absorption such as five-photon absorption offers significant advantages of greater spatial confinement, increased penetration depth, reduced autofluorescence, enhanced sensitivity and improved resolution over lower orders in bioimaging. Organic chromophores and conventional semiconductor nanocrystals are leaders in two-/three-photon absorption applications, but face considerable challenges from their small five-photon action cross-sections. Herein, we reveal that the family of halide perovskite colloidal nanocrystals transcend these constraints with highly efficient five-photon-excited upconversion fluorescence—unprecedented for semiconductor nanocrystals. Amazingly, their multidimensional type I (both conduction and valence band edges of core lie within bandgap of shell) core–shell (three-dimensional methylammonium lead bromide/two-dimensional octylammonium lead bromide) perovskite nanocrystals exhibit five-photon action cross-sections that are at least 9 orders larger than state-of-the-art specially designed organic molecules. Importantly, this family of halide perovskite nanocrystals may enable fresh approaches for next-generation multiphoton imaging applications.||URI:||https://hdl.handle.net/10356/88612
|DOI:||http://dx.doi.org/10.1038/ncomms15198||Rights:||© 2017 The Author(s) (Nature Publishing Group). This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/||Fulltext Permission:||open||Fulltext Availability:||With Fulltext|
|Appears in Collections:||SPMS Journal Articles|
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