dc.contributor.authorWongchitphimon, Sunee
dc.contributor.authorRongwong, Wichitpan
dc.contributor.authorChuah, Chong Yang
dc.contributor.authorWang, Rong
dc.contributor.authorBae, Tae-Hyun
dc.identifier.citationWongchitphimon, S., Rongwong, W., Chuah, C. Y., Wang, R., & Bae, T.-H. (2017). Polymer-fluorinated silica composite hollow fiber membranes for the recovery of biogas dissolved in anaerobic effluent. Journal of Membrane Science, 540, 146-154.en_US
dc.description.abstractIn this study, polymer-fluorinated silica composite hollow fiber membranes were fabricated and applied to a membrane contactor system for the recovery of methane dissolved in the anaerobic effluent. Such composite membranes allowed us to tailor the physical property such as porosity and mechanical strength and the surface hydrophobicity in separated processes. To develop the composite membranes, porous hollow fiber substrates were first fabricated with Matrimid®, a commercial polyimide. Subsequently, fluorinated silica particles were synthesized and anchored on the substrates via a strong covalent bonding. Due to the high porosity as well as the high hydrophobicity, our membrane showed an outstanding performance for the recovery of CH4 in the membrane contactor, such that the CH4 flux reached 2900 mg CH4/m2–h at the liquid velocity of 0.42 m/s at which the liquid phase still controlled the overall mass transfer. The composite membrane prepared in this work also showed a much better performance in the CH4 recovery than a commercial polypropylene membrane made for degasification of water. In addition, a long-term test with tap water saturated with the model biogas made up of 60:40 CH4/CO2 mixture demonstrated that our membrane can be stably operated for more than 300 h without experiencing pore wetting problem.en_US
dc.description.sponsorshipNRF (Natl Research Foundation, S’pore)en_US
dc.description.sponsorshipEDB (Economic Devt. Board, S’pore)en_US
dc.format.extent33 p.en_US
dc.relation.ispartofseriesJournal of Membrane Scienceen_US
dc.rights© 2017 Elsevier B.V. This is the author created version of a work that has been peer reviewed and accepted for publication by Journal of Membrane Science, Elsevier B.V. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1016/j.memsci.2017.06.050].en_US
dc.subjectDissolved Methane Recoveryen_US
dc.titlePolymer-fluorinated silica composite hollow fiber membranes for the recovery of biogas dissolved in anaerobic effluenten_US
dc.typeJournal Article
dc.contributor.researchNanyang Environment and Water Research Instituteen_US
dc.contributor.researchSingapore Membrane Technology Centreen_US
dc.contributor.schoolSchool of Chemical and Biomedical Engineeringen_US
dc.contributor.schoolSchool of Civil and Environmental Engineeringen_US
dc.description.versionAccepted versionen_US

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