Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/88918
Title: Site‐Selective Catalysis of a Multifunctional Linear Molecule: The Steric Hindrance of Metal–Organic Framework Channels
Authors: Zhang, Weina
Zheng, Bing
Shi, Wenxiong
Chen, Xinyi
Xu, Zhiling
Li, Shuzhou
Chi, Robin Yonggui
Yang, Yanhui
Lu, Jun
Huang, Wei
Huo, Fengwei
Keywords: Metal Nanoparticles
Metal–organic Frameworks
Issue Date: 2018
Source: Zhang, W., Zheng, B., Shi, W., Chen, X., Xu, Z., Li, S., et al. (2018). Site‐Selective Catalysis of a Multifunctional Linear Molecule: The Steric Hindrance of Metal–Organic Framework Channels. Advanced Materials, in press.
Series/Report no.: Advanced Materials
Abstract: The site‐selective reaction of a multifunctional linear molecule requires a suitable catalyst possessing both uniform narrow channel to limit the molecule rotation and a designed active site in the channel. Recently, nanoparticles (NPs) were incorporated in metal–organic frameworks (MOFs) with the tailorable porosity and ordered nanochannel, which makes these materials (NPs/MOFs) highly promising candidates as catalytic nanoreactors in the field of heterogeneous catalysis. Inspired by a “Gondola” sailing in narrow “Venetian Canal” without sufficient space for a U‐turn, a simple heterogeneous catalyst based on NPs/MOFs is developed that exhibits site‐selectivity for the oxidation of diols by restricting the random rotation of the molecule (the “Gondola”) in the limited space of the MOF channel (the narrow “Venetian Canal”), thereby protecting the middle functional group via steric hindrance. This strategy is not limited to the oxidation of diols, but can be extended to the site‐selective reaction of many similar multifunctional linear molecules, such as the reduction of alkadienes.
URI: https://hdl.handle.net/10356/88918
http://hdl.handle.net/10220/44788
ISSN: 0935-9648
DOI: http://dx.doi.org/10.1002/adma.201800643
Rights: © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. This is the author created version of a work that has been peer reviewed and accepted for publication by Advanced Materials, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1002/adma.201800643].
metadata.item.grantfulltext: open
metadata.item.fulltext: With Fulltext
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