Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/87756
Title: Solvent dependent disorder in M2(BzOip)2(H2O)·solvate (M = Co or Zn)
Authors: Teat, Simon J.
McCormick, Laura J.
Morris, Samuel Alexander
Morris, Russell E.
Slawin, Alexandra M. Z.
Keywords: X-ray Crystallography
Solvothermal
Issue Date: 2017
Source: McCormick, L. J., Morris, S. A., Teat, S. J., Slawin, A. M. Z., & Morris, R. E. (2018). Solvent dependent disorder in M2(BzOip)2(H2O)·solvate (M = Co or Zn). Crystals, 8(1), 6-.
Series/Report no.: Crystals
Abstract: Coordination polymers derived from 5-benzyloxy isophthalic acid (H2BzOip) are rare, with only three reported that do not contain additional bridging ligands, of which two M2(BzOip)2(H2O) (M = Co and Zn) are isomorphous. It was hoped that by varying the solvent system in a reaction between H2BzOip and M(OAc)2 (M = Co and Zn), from water to a water/alcohol mixture, coordination polymers of different topology could be formed. Instead, two polymorphs of the existing M2(BzOip)2(H2O) (M = Co and Zn) were isolated from aqueous methanol and aqueous ethanol, in which a small number of guest solvent molecules are present in the crystals. These guest water molecules disrupt the hexaphenyl embrace motif, leading to varying degrees of disorder of the benzyl groups.
URI: https://hdl.handle.net/10356/87756
http://hdl.handle.net/10220/45540
ISSN: 2073-4352
DOI: http://dx.doi.org/10.3390/cryst8010006
Rights: © 2017 The Author(s). Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:MSE Journal Articles

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