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|Title:||Solvent dependent disorder in M2(BzOip)2(H2O)·solvate (M = Co or Zn)||Authors:||Teat, Simon J.
McCormick, Laura J.
Morris, Samuel Alexander
Morris, Russell E.
Slawin, Alexandra M. Z.
|Issue Date:||2017||Source:||McCormick, L. J., Morris, S. A., Teat, S. J., Slawin, A. M. Z., & Morris, R. E. (2018). Solvent dependent disorder in M2(BzOip)2(H2O)·solvate (M = Co or Zn). Crystals, 8(1), 6-.||Series/Report no.:||Crystals||Abstract:||Coordination polymers derived from 5-benzyloxy isophthalic acid (H2BzOip) are rare, with only three reported that do not contain additional bridging ligands, of which two M2(BzOip)2(H2O) (M = Co and Zn) are isomorphous. It was hoped that by varying the solvent system in a reaction between H2BzOip and M(OAc)2 (M = Co and Zn), from water to a water/alcohol mixture, coordination polymers of different topology could be formed. Instead, two polymorphs of the existing M2(BzOip)2(H2O) (M = Co and Zn) were isolated from aqueous methanol and aqueous ethanol, in which a small number of guest solvent molecules are present in the crystals. These guest water molecules disrupt the hexaphenyl embrace motif, leading to varying degrees of disorder of the benzyl groups.||URI:||https://hdl.handle.net/10356/87756
|ISSN:||2073-4352||DOI:||http://dx.doi.org/10.3390/cryst8010006||Rights:||© 2017 The Author(s). Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).||Fulltext Permission:||open||Fulltext Availability:||With Fulltext|
|Appears in Collections:||MSE Journal Articles|
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