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|Title:||Fusing N-heteroacene analogues into one “kinked” molecule with slipped two-dimensional ladder-like packing||Authors:||Zhang, Jing
|Issue Date:||2016||Source:||Zhang, J., Wang, C., Long, G., Aratani, N., Yamada, H., & Zhang, Q. (2016). Fusing N-heteroacene analogues into one “kinked” molecule with slipped two-dimensional ladder-like packing. Chemical Science, 7(2), 1309-1313. doi:10.1039/C5SC03604F||Series/Report no.:||Chemical Science||Abstract:||An unexpected “kinked” N-heteroacene with a slipped two-dimensional ladder-like packing feature is produced from the conventional condensation reaction. The as-obtained compound [2,2′]bi(5,12-bis(TIPS)piperazin-3-one[2,3-b]phenazine) (2BPP) consists of two identical backbones (5,12-bis(TIPS)piperazin-3-one[2,3-b]phenazine), which are fused together through a C[double bond, length as m-dash]C double bond and two intramolecular H-bonds. A study on the charge carrier transport indicates that a 2BPP single crystal has a hole mobility up to 0.3 cm2 V−1 s−1, while theoretical calculations suggest that this compound might possess potential well-balanced ambipolar charge-transport characteristics.||URI:||https://hdl.handle.net/10356/90202
|ISSN:||2041-6520||DOI:||10.1039/C5SC03604F||Rights:||© 2016 The Author(s) (published by Royal Society of Chemistry). This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.||Fulltext Permission:||open||Fulltext Availability:||With Fulltext|
|Appears in Collections:||MSE Journal Articles|
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