dc.contributor.authorZhang, Qiuchi
dc.date.accessioned2019-01-31T13:32:35Z
dc.date.available2019-01-31T13:32:35Z
dc.date.issued2019-01-31
dc.identifier.citationZhang, Q. (2019). Part I α,β-dehydrogenation of carbonyl compounds via selenium reagents elimination Part II Indium catalyzed cyclization reaction of acrylate. Doctoral thesis, Nanyang Technological University, Singapore.
dc.identifier.urihttp://hdl.handle.net/10220/47601
dc.description.abstractIn in first part, selenium conducted elimination reaction of thioesters was discussed. This is a two-step one-pot reaction, which firstly give an alpha selenium substitute of thioesters, then oxidize the selenium intermediate gives an elimination reaction, which lead to the α,β-unsaturated thioester as the product. In in second part, an In(III)-TMSBr-catalyzed aryldihydronaphthalene derivatives synthesis method is discussed, the indium catalyst makes the aryl alkyne react with two molecules of acrylate and gives an aryldihydronaphthalene derivative as the product.en_US
dc.format.extent170 p.en_US
dc.language.isoenen_US
dc.subjectDRNTU::Science::Chemistry::Organic chemistry::Oxidationen_US
dc.subjectDRNTU::Science::Chemistry::Organic chemistry::Organic synthesisen_US
dc.subjectDRNTU::Science::Chemistry::Organic chemistry::Organometallic compoundsen_US
dc.subjectDRNTU::Science::Chemistry::Organic chemistry::Organic spectroscopyen_US
dc.titlePart I α,β-dehydrogenation of carbonyl compounds via selenium reagents elimination Part II Indium catalyzed cyclization reaction of acrylateen_US
dc.typeThesis
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.contributor.supervisorLi Tianhuen_US
dc.contributor.supervisorLoh Teck Pengen_US
dc.description.degreeDoctor of Philosophyen_US
dc.identifier.doihttps://doi.org/10.32657/10220/47601


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