dc.contributor.authorJiao, Zhiwei
dc.contributor.authorLim, Li Hui
dc.contributor.authorHirao, Hajime
dc.contributor.authorZhou, Steve Jianrong
dc.date.accessioned2019-05-21T07:37:50Z
dc.date.available2019-05-21T07:37:50Z
dc.date.issued2018
dc.identifier.citationJiao, Z., Lim, L. H., Hirao, H., & Zhou, S. J. (2018). Palladium-catalyzed para-selective alkylation of electron-deficient arenes. Angewandte Chemie International Edition, 57(21), 6294-6298. doi:10.1002/anie.201801967en_US
dc.identifier.issn1433-7851en_US
dc.identifier.urihttp://hdl.handle.net/10220/48297
dc.description.abstractIntermolecular alkylations of electron‐deficient arenes proceed with good para selectivity. Palladium catalysts were used to generate nucleophilic alkyl radicals from alkyl halides, which then directly add onto the arenes. The arene scope and the site of alkylation are opposite to those of classical Friedel–Crafts alkylations, which prefer electron‐rich systems.en_US
dc.description.sponsorshipMOE (Min. of Education, S’pore)en_US
dc.format.extent6 p.en_US
dc.language.isoenen_US
dc.relation.ispartofseriesAngewandte Chemie International Editionen_US
dc.rights© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. This is the peer reviewed version of the following article: Jiao, Z., Lim, L. H., Hirao, H., & Zhou, S. J. (2018). Palladium-catalyzed para-selective alkylation of electron-deficient arenes. Angewandte Chemie International Edition, 57(21), 6294-6298, which has been published in final form at http://dx.doi.org/10.1002/anie.201801967. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.en_US
dc.subjectAlkyl Radicalsen_US
dc.subjectAlkylationen_US
dc.subjectDRNTU::Science::Chemistryen_US
dc.titlePalladium-catalyzed para-selective alkylation of electron-deficient arenesen_US
dc.typeJournal Article
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doihttp://dx.doi.org/10.1002/anie.201801967
dc.description.versionAccepted versionen_US


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