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|Title:||Ag embedded Li3VO4 as superior anode for Li-ion batteries||Authors:||Kang, Tao
|Issue Date:||2019||Source:||Kang, T., Ni, S., Chen, Q., Li, T., Chao, D., Yang, X., & Zhao, J. (2019). Ag embedded Li3VO4 as superior anode for Li-ion batteries. Journal of The Electrochemical Society, 166(3), A5295-A5300. doi:10.1149/2.0381903jes||Series/Report no.:||Journal of The Electrochemical Society||Abstract:||Highly conductive Ag is proven effective to improve the electrochemical performance of Li3VO4. Ag@Li3VO4 composite with unique architecture of Ag nanoparticles embedded homogeneously in Li3VO4 matrix is prepared by a facile intermediate solution method. The Ag@Li3VO4 delivers high initial discharge and charge capacities of 651 and 479 mAh g−1 at a specific current of 0.15 A g−1, maintaining of 498 and 492 mAh g−1 after 150 cycles. Superior rate capability (364 mAh g−1) can be achieved at 1.5 A g−1, with more than 5 times improvement compared the one without Ag decoration. Herein, conductive but inert Ag is found facilitating fast Li+ ion storage of the Li3VO4 owing to enhanced electronic conductivity, Li ion diffusion, and structure stability, distinctly improving cycle stability and rate performance.||URI:||https://hdl.handle.net/10356/85222
|ISSN:||0013-4651||DOI:||http://dx.doi.org/10.1149/2.0381903jes||Rights:||© 2019 The Author(s). Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY, http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium, provided the original work is properly cited.||Fulltext Permission:||open||Fulltext Availability:||With Fulltext|
|Appears in Collections:||SPMS Journal Articles|
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