dc.contributor.authorZhao, Yanli
dc.contributor.authorLiu, Yu
dc.identifier.citationZhao, Y., & Liu, Y. (2006). Self-assembly behavior of phenyl modified β-cyclodextrins. Science in China Series B: Chemistry, 49(3), 230-237.en_US
dc.description.abstractThe self-assembly behavior of mono(6-phenolic-6-deoxy)-β-cyclodextrin (1) both in solution and the solid state is comparatively studied by X-ray crystallography and 1H NMR spectroscopy. The results obtained show that the phenolic groups in the crystal 1 can successively penetrate into the adjacent β-cyclodextrin cavities from the secondary side to form head-to-tail linear polymeric supramolecule with a 2-fold screw axis. The self-assembly behavior also can be determined in D2O solution, giving a self-association constant of 240 mol−1⋅L. Using the present and previous structures reported for the relevant β-cyclodextrin derivatives, i.e., mono(6-anilino-6-deoxy)-β-cyclodextrin (2), mono(6-phenylselenyl-6-deoxy)-β-cyclodextrin (3), and mono(6-phenylthio-6-deoxy)-β-cyclodextrin (4), we further reveal the factors governing the formations of supramolecular assemblies.en_US
dc.format.extent8 p.
dc.relation.ispartofseriesScience in China series B: Chemistryen_US
dc.rights© 2006 Springer. This is the author created version of a work that has been peer reviewed and accepted for publication by Science in China Series B: Chemistry, Springer. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at DOI: http://dx.doi.org/10.1007/s11426-006-0230-y.en_US
dc.subjectDRNTU::Science::Biological sciences::Biochemistry
dc.titleSelf-assembly behavior of phenyl modified β-cyclodextrinsen_US
dc.typeJournal Article
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.description.versionAccepted versionen_US

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