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|Title:||Brønsted acid catalyzed α-alkylation of aldehydes with diaryl methyl alcohols||Authors:||Xing, Chong
Chi, Robin Yonggui
|Issue Date:||2011||Source:||Xing, C., Sun, H., Zhang, J., Li, G. & Chi, R. Y. (2011). Brønsted Acid Catalyzed α-Alkylation of Aldehydes with Diaryl Methyl Alcohols. Chemistry - A European Journal, 17(44), 12272-12275.||Series/Report no.:||Chemistry - a European journal||Abstract:||A proton does the two jobs: Brønsted acids alone catalyze the α-alkylation of aldehydes with diaryl alcohols. In this type of transformation, the acid-catalysis approach offers a broader substrate scope compared to the previously used enamine catalysis methods. The acid plays two important roles: one is to mediate the alcohol dehydration for carbocation formation; the other is to accelerate the rate-determining aldehyde enolization.||URI:||https://hdl.handle.net/10356/94631
|DOI:||http://dx.doi.org/10.1002/chem.201102623||Rights:||© 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.||Fulltext Permission:||none||Fulltext Availability:||No Fulltext|
|Appears in Collections:||SPMS Journal Articles|
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